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For low-power microcontroller WiFi, check out the Adafruit CC3000 breakouts and shields. The CC3000 hits that sweet spot of usability, price and capability. It uses SPI for communication (not UART!) so you can push data as fast as you want or as slow as you want. It has a proper interrupt system with IRQ pin so you can have asynchronous connections. It supports 802.11b/g, open/WEP/WPA/WPA2 security, TKIP & AES. A built in TCP/IP stack with a "BSD socket" interface. TCP and UDP in both client and server mode, up to 4 concurrent sockets.